Calculation

2024-11-21


Calculation


 

There are different ways of doing the calculations. Most commonly used methods are the %NCO and the amine equivalent method.

 

%NCO Method


 

 

The calculation is to determine the amount of curative needed for 100 parts by weight of the prepolymer.

Where

%NCO is the amount of terminal isocyanate in the prepolymer and is supplied by the manufacturer and is marked on the can EW curative is supplied by the manufacturer of the curative EW NCO is the equivalent weight of the isocyanate group and is 42.02 %Theory is the variation required to give the best properties for the system

 

 The formula is normally used in a simplified form. For example, if we are using MOCA as the curing agent and the index at 95%,  

 

Amine Equivalent Method


 

 

The other method that is sometimes proposed is the “amine equivalent”(AE) method:

 

Common Curatives


 

 

TCurative are used to enlarge the prepolymer chain either by extension or by cross-linking. Materials with two active groups will extend the length of the chain by joining two chains together. Triols will provide the means to form permanent covalent bonds between different chains.

 

Type Name Equivalent Wt.
Diol BDO 45
HQEE 99.1
High M/W Diols PPG1000 500
PTMEG1000 500
Triols TIPA 63.7
TMP 44.7
Diamine Ethacure E100 89.3
Ethacure E300 107
M-CDEA 187
MOCA(MBOCA) 133.5

The equivalent weight of the blend must be calculated taking into account the individual equivalent weights.

For example, if a mixture of 3parts TMP is used with 1 parts of TIPA,

The above calculation gives a working EW of 48.3.

Calculation


 

There are different ways of doing the calculations. Most commonly used methods are the %NCO and the amine equivalent method.

 

%NCO Method


 

 

The calculation is to determine the amount of curative needed for 100 parts by weight of the prepolymer.

Where

%NCO is the amount of terminal isocyanate in the prepolymer and is supplied by the manufacturer and is marked on the can EW curative is supplied by the manufacturer of the curative EW NCO is the equivalent weight of the isocyanate group and is 42.02 %Theory is the variation required to give the best properties for the system

 

 The formula is normally used in a simplified form. For example, if we are using MOCA as the curing agent and the index at 95%,  

 

Amine Equivalent Method


 

 

The other method that is sometimes proposed is the “amine equivalent”(AE) method:

 

Common Curatives


 

 

TCurative are used to enlarge the prepolymer chain either by extension or by cross-linking. Materials with two active groups will extend the length of the chain by joining two chains together. Triols will provide the means to form permanent covalent bonds between different chains.

 

Type Name Equivalent Wt.
Diol BDO 45
HQEE 99.1
High M/W Diols PPG1000 500
PTMEG1000 500
Triols TIPA 63.7
TMP 44.7
Diamine Ethacure E100 89.3
Ethacure E300 107
M-CDEA 187
MOCA(MBOCA) 133.5

The equivalent weight of the blend must be calculated taking into account the individual equivalent weights.

For example, if a mixture of 3parts TMP is used with 1 parts of TIPA,

The above calculation gives a working EW of 48.3.